Product ID:ACL 60 CHLORINATING COMPOSITION
MSDS Date:07/21/1989
FSC:6850
NIIN:00N041989
MSDS Number: BTLLG

MONSANTO CO

800 NORTH LINDBERGH BLVD
ST LOUIS, MO 63167
US

Emergency Phone: 314-694-1000

Info Phone: 314-694-1000

Cage: 76541

MONSANTO COMPANY

SAINT LOUIS, MO 63167 US

Telephone: 314-694-6661 OR 800-332-3111

Cage: 76541

CLEANUP ON DRY BASIS IF POSS. FLOOR SWEEPING CMPD

RTECS: 9999999ZZ

MAY RSLT. WEAR PROT EQUIP. WASTES OF UNNEUT PROD ARE

RTECS: 9999999ZZ

& REACTIVITY UNDER CERCLA. IF 100 LBS/MORE OF STORED

RTECS: 9999999ZZ

NATL RESPONSE CTR. SINCE LOCAL, STATE & FED LAWS

RTECS: 9999999ZZ

REGARDING SPILL RPTG. KEEP UNNEUT PROD OUT OF

RTECS: 9999999ZZ

LABEL INSTRUCTIONS, CNTCT STATE

RTECS: 9999999ZZ

REGIONAL OFFICE FOR GUIDANCE.

RTECS: 9999999ZZ

LIMITATIONS SPECIFIED BY NIOSH/MSHA/MFR MUST BE

RTECS: 9999999ZZ

SUPPLIED AIR RESP. RESP PROT PROGRAMS MUST BE IN

RTECS: 9999999ZZ

OPEN PROCESS EQUIP.

RTECS: 9999999ZZ

S-TRIAZINE-2,4,6(1H,3H,5H)-TRIONE, DICHLORO-,SODIUM SALT;

CAS: 2893-78-9

RTECS: XZ1900000

Fraction By Weight: 96%

OSHA PEL 0.5PPM, 1PPM STEL

ACGIH TLV: 0.5PPM, 1PPM STEL

CHLORINE

CAS: 7782-50-5

RTECS: FO2100000

Fraction By Weight: 62%

OSHA PEL 0.5 PPM; 1 STEL

ACGIH TLV: 0.5 PPM; 1 STEL

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

OTHER INGREDIENTS

Fraction By Weight: 4%

OSHA PEL N/K

ACGIH TLV: N/K

W/EASILY OXIDIZABLE ORG MATL; AMMONIA,

RTECS: 9999999ZZ

CMPDS; CALCIUM HYPOCHLORITE; ALKALIS.

RTECS: 9999999ZZ

HDCH, DIZZ & SYNCOPE. ONSET OF SEV RESP

RTECS: 9999999ZZ

& PNEUM, MAY BE DELAYED.

RTECS: 9999999ZZ

DMG MAY CONTRAINDICATE USE OF GASTRIC

RTECS: 9999999ZZ

SPILLED MATL, CONTAMD SOIL & OTHER CONTAMD MATL

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50: (ORAL, RAT) 700 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CORR TO EYES & SKIN. EXPOS TO PROD
DUST/FUMES RPTD TO PRODUCE EYE, NOSE, THROAT, & RESP TRACT IRRIT.
ON CNTCT W/MOISTURE, PROD READILY HYDROLYSES TO HYPOCHLOROUS ACID &
CYANURIC ACID. TISS DMG RSLTG F ROM CNTCT W/PROD IS CONSIDERED TO
RSLT,IN PART, FROM ITS HYPOCHLOROUS ACID DECOMP PRODS. VAP SPACE IN
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:CLSD CONTR OF PROD MAY CONTAIN SLIGHT
AMT CHLORINE GAS & OTHER CHLORINE CMPDS FROM DECOMP OF PROD. EXPOS
TO CHLORINE GAS RPTD CAUSE BURNING OF EYES W/LACRIMATION; BURNING
NOSE & MOUTH W/RHINO RRHEA; & IRRIT OF LININGS OF ENTIRE RESP TRACT
W/COUGHING, CHOKING SENSATION, SUBSTERNAL PAIN, VOMIT, NAUS, (ING
6)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST:PROMPTLY DRINK 1-2 LG GLASSES WATER/MILK. DO NOT
INDUCE VOMIT. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS. GET MED
ATTN. AVOID ALCOHOL. EYES:FLUSH W/PLENTY WATER FOR @ LEAST 15 MINS.
GET MED AT TN. INHAL:REMOVE TO FRESH AIR. CALL MD.SKIN:FLUSH
W/COPIOUS AMTS WATER (DELUGE SHOWER) FOR @ LEAST 15 MIN. REMOVE
CONTAMD GARMENTS UNDER SHOWER. CALL MD . NOTE TO MD:PROBABLE
MUCOSAL (ING 8)

Flash Point:NONFLAMMABLE
Extinguishing Media:THERMAL DECOMP EXTING BY FLOODING W/COPIOUS QTYS
WATER/ISOLATING DECOMP MATL & ALLOWING TO BE CONSUMED. DO NOT
(SUPDAT)
Fire Fighting Procedures:NIOSH/MSHA APPROVED SCBA & FULL PROT EQUIP .
IF POSS, ISOLATE CONTR IN OPEN AIR/WELL VENT AREA. FLOOD W/LG VOL
WATER. CHLORINE CONTAINING GASES (SUPDAT)
Unusual Fire/Explosion Hazard:NITROGEN TRICHLORIDE CAN BE GENERATED BY
RXN OF WATER W/PROD UNDER CERTAIN CNDTNS OF PH, CONC & TEMP. RXN OF
H*2O W/ACL 60 GENLY NOT EXPLOS HAZ AS RATE (SUPDAT)

Spill Release Procedures:FOR CONCENTRATED PROD:CONTAIN SPILLED MATL.
SPILLAGE SHLD BE CLEANED UP ASAP TO PVNT CONTAM W/FOREIGN MATL
W/WHICH IT MAY REACT. KEEP SPILLED MATL DRY. IF ALLOWED TO STAND IN
DAMP/WET AREA, TEAR-PRODU CING VAPS MAY RSLT. SWEEP/SCOOP/VACUUM
(ING 9)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:RETIE POLYETHYLENE LINER AFTER EACH
USE & KEEP CONTR TIGHTLY CLOSED. STORE IN DRY PLACE. DO NOT ALLOW
WATER INTO CONTR. KEEP CONTR OFF WET FLOORS.
Other Precautions:DO NOT CONTAM WATER/FOOD/FEED BY STORAGE/DISPOSAL.
PROD TOX TO FISH. DO NOT DISCHARGE INTO LAKES/STREAMS/PONDS/PUBLIC
WATERS UNLESS I/A/W NPDES PERMIT. FOR GUIDANCE CNTCT REGIONAL
OFFICE OF EPA.

Respiratory Protection:AVOID BRTHG DUST. USE NIOSH/MSHA APPRVD EQUIP
WHEN AIRBORNE EXPOS LIMS EXCEEDED. FULL FCPIECE EQUIP RECOM & IF
USED, REPLACES NEED FOR FCSHLD &/OR CHEM SPLASH GOGG. CONSULT RESP
MFR FOR TYPE EQUIP FOR GIVEN APPLICATN. RESP USE (ING 17)
Ventilation:TO CONTROL EXPOS LEVELS BELOW AIRBORNE EXPOS LIM. USE LOC
MECH EXHAUST VENT @ SOURCES OF AIR CONTAM SUCH AS (ING 19)
Protective Gloves:CONSULT GLOVE MFR FOR APPROP TYPE.
Eye Protection:CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:PROTECTIVE CLTHG. PROVIDE EMERGENCY EYE WASH
& DELUGE SHOWER @ ANY LOCATION WHERE SKIN CNTCT CAN OCCUR.
Work Hygienic Practices:WASH IMMED IF SKIN CONTAMD. LAUNDER CONTAMD
CLTHG & CLEAN PROT EQUIP BEFORE REUSE. WASH THORO AFTER HNDLG.
Supplemental Safety and Health
PH:6 (1% SOLN). EXTING MEDIA:USE ABC DRY CHEM EXTING SINCE POTENTIAL
FOR VIOLENT RXN. FIRE FIGHT PROC: W/TRACES OF PHOSGENE CAN BE
LIBERATED @ TEMP > 400F. THOROUGHLY DECONTAM FIREFIGHTING EQUIP
INCL FIREFIGHTING WEARING APPAREL AFTER INCIDENT. EXPLO HAZ: OF
NITROGEN TRICHLORIDE FORM VERY SLOW.

HCC:N1
Melt/Freeze Pt:M.P/F.P Text:>464F,>240C
Decomp Temp:Decomp Text:>464F,>240C
pH:SUPDAT
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:25G/100G H*2O
Appearance and Odor:WHITE CRYSTALLINE SOLID. SLIGHT CHLORINE ODOR.

Stability Indicator/Materials to Avoid:YES
AVOID CNTCT W/WATER ON CONCENTRATED PROD IN CONTR:FORMS HYPOCHLOROUS
ACID & CYANURIC ACID. ALSO AVOID CNTCT (ING 4)
Stability Condition to Avoid:PREPARATION OF CONCENTRATED SOLNS/SLURRIES
OF PROD NOT RECOMND.
Hazardous Decomposition Products:CHLORINE-CONTAINING GASES. TRACES OF
PHOSGENE CAN BE LIBERATED AT TEMPS >400F/WHEN PROD CONTAMD.

Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE, & LOCAL LAWS &
REGS. WASTES MAY CAUSE IRREVERSIBLE EYE DMG & BURNS TO SKIN & MAY
BE DANGEROUS. IMPROPER DISP OF EXCESS PESTICIDE/SPRAY MIX/RINSATE
IS VIOLATION OF FED LA W. IF CANNOT BE DISPOSED OF ACCDG TO (ING
15)

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particular situation.